Ashling CWMacreadie LKSouthern TJFZhang YMcHugh LNEvans RCKaskel STelfer SGBennett TD2024-01-112024-07-252021-03-012024-01-112024-07-252021-03-01Ashling CW, Macreadie LK, Southern TJF, Zhang Y, McHugh LN, Evans RC, Kaskel S, Telfer SG, Bennett TD. (2021). Guest size limitation in metal-organic framework crystal-glass composites. Journal of Materials Chemistry A. 9. 13. (pp. 8386-8393).2050-7488https://mro.massey.ac.nz/handle/10179/70837Metal-organic framework crystal-glass composites (MOF CGCs) have previously been formed by embedding crystalline MIL-53(Al) within a ZIF-62 glass (agZIF-62) matrix. Here we highlight thermal stability considerations in the formation of MOF CGCs, and subsequently report the synthesis of two novel MOF CGCs, by incorporating MIL-118 and UL-MOF-1 withinagZIF-62. These new materials, alongside the prototypical MOF CGC, formed using MIL-53(Al), were studied using scanning electron microscopy, powder X-ray diffraction, and gas sorption techniques. The gas uptake in composites formed from MIL-118C and UL-MOF-1 is largely dominated by theagZIF-62 matrix, suggesting that to improve the porosity of the MOF CGC, the matrix porosity must be improved, or a percolation threshold must be overcome.CC BY 3.0https://creativecommons.org/licenses/by/3.0/Journal article10.1039/d0ta11229a2050-7496journal-article8386-8393http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000637555800019&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=c5bb3b2499afac691c2e3c1a83ef6fef