Browsing by Author "Chen B"

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    How Reproducible are Surface Areas Calculated from the BET Equation?
    (Wiley-VCH GmbH, 2022-05-23) Osterrieth JWM; Rampersad J; Madden D; Rampal N; Skoric L; Connolly B; Allendorf MD; Stavila V; Snider JL; Ameloot R; Marreiros J; Ania C; Azevedo D; Vilarrasa-Garcia E; Santos BF; Bu X-H; Chang Z; Bunzen H; Champness NR; Griffin SL; Chen B; Lin R-B; Coasne B; Cohen S; Moreton JC; Colón YJ; Chen L; Clowes R; Coudert F-X; Cui Y; Hou B; D'Alessandro DM; Doheny PW; Dincă M; Sun C; Doonan C; Huxley MT; Evans JD; Falcaro P; Ricco R; Farha O; Idrees KB; Islamoglu T; Feng P; Yang H; Forgan RS; Bara D; Furukawa S; Sanchez E; Gascon J; Telalović S; Ghosh SK; Mukherjee S; Hill MR; Sadiq MM; Horcajada P; Salcedo-Abraira P; Kaneko K; Kukobat R; Kenvin J; Keskin S; Kitagawa S; Otake K-I; Lively RP; DeWitt SJA; Llewellyn P; Lotsch BV; Emmerling ST; Pütz AM; Martí-Gastaldo C; Padial NM; García-Martínez J; Linares N; Maspoch D; Suárez Del Pino JA; Moghadam P; Oktavian R; Morris RE; Wheatley PS; Navarro J; Petit C; Danaci D; Rosseinsky MJ; Katsoulidis AP; Schröder M; Han X; Yang S; Serre C; Mouchaham G; Sholl DS; Thyagarajan R; Siderius D; Snurr RQ; Goncalves RB; Telfer S; Lee SJ; Ting VP; Rowlandson JL; Uemura T; Iiyuka T; van der Veen MA; Rega D; Van Speybroeck V; Rogge SMJ; Lamaire A; Walton KS; Bingel LW; Wuttke S; Andreo J; Yaghi O; Zhang B; Yavuz CT; Nguyen TS; Zamora F; Montoro C; Zhou H; Kirchon A; Fairen-Jimenez D
    Porosity and surface area analysis play a prominent role in modern materials science. At the heart of this sits the Brunauer-Emmett-Teller (BET) theory, which has been a remarkably successful contribution to the field of materials science. The BET method was developed in the 1930s for open surfaces but is now the most widely used metric for the estimation of surface areas of micro- and mesoporous materials. Despite its widespread use, the calculation of BET surface areas causes a spread in reported areas, resulting in reproducibility problems in both academia and industry. To prove this, for this analysis, 18 already-measured raw adsorption isotherms were provided to sixty-one labs, who were asked to calculate the corresponding BET areas. This round-robin exercise resulted in a wide range of values. Here, the reproducibility of BET area determination from identical isotherms is demonstrated to be a largely ignored issue, raising critical concerns over the reliability of reported BET areas. To solve this major issue, a new computational approach to accurately and systematically determine the BET area of nanoporous materials is developed. The software, called "BET surface identification" (BETSI), expands on the well-known Rouquerol criteria and makes an unambiguous BET area assignment possible.
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    The Value Cocreation Influence Mechanism of Network Freight Transport Platform in IoT-Based Environments: Under the Service-Dominant Logic
    (John Wiley and Sons, 2021-05-24) Bai P; Wu Q; Li Q; Zhang L; Jiang Y; Chen B; Wang W
    The Internet of Things (IoT) has brought many benefits to the development of industries, from manufacturing to services. In the context of IoT, the network freight transport platform is equivalent to an integrator, integrating the scattered resources such as carriers and shippers in the supply chain, providing a solution, improving the use efficiency of vehicles, effectively reducing logistics cost, and creating value for the freight transport platform and bilateral customers. The purpose of this research is to explain the influence mechanism of transport demand subjects' participation in value cocreation (VCC) under the service-dominant logic (SDL). We proposed a conceptual framework and 10 hypotheses and used SEM to measure the direct and mediating relationship among SDL, transport demand subject (TDS) participation, relational embeddedness (RE), platform VCC, and TDS value in the online business environment. The findings show that (1) SDL, TDS participation, and RE do not directly affect the TDS value, but indirectly through platform VCC; (2) SDL affects platform VCC not only directly but also indirectly through TDS participation and RE; (3) TDS participation affects platform VCC not only directly but also indirectly through RE; (4) RE indirectly affects TDS value by affecting platform VCC; and (5) platform VCC plays a mediating role in SDL, TDS participation, RE, and TDS value. Hence, transport enterprises should pay attention to the innovation concept, guide TDS participation, jointly improve platform VCC, give play to the network effect of the freight transport platform, and achieve TDS value through the deepening of TDS relationship embedding.