Browsing by Author "Swanson, Adam James"
Now showing 1 - 2 of 2
Results Per Page
Sort Options
- ItemThe Raman spectroscopy of ionic liquids : a thesis presented in partial fulfilment of the requirements for the degree of Master of Science in Chemical Physics at Massey University, New Zealand(Massey University, 2007) Swanson, Adam JamesRaman and infrared spectra were recorded for the ionic liquids [CH3N(C4H8)Bu]+[(F3CSO2)2N]-, [Et3NH]+[(octyl)PO2H]-, [Bu4N]+[(hexyl)PO2H]-, and [Bu4P]+[(octyl)2PO2]- and was compared to spectra calculated by Gaussian 03 using the density functional theory method B3LYP. The experimental and calculated spectra were found to be very similar, indicating that no underlying anomalous effects were perturbing the vibrational modes. The peaks of the experimental and calculated Raman and infrared spectra were found to be broad and intertwined, because of the close proximity of numerous vibrational bands. The differential and absolute scattering cross sections of selected bands of the ionic liquids were determined using a method of comparing the area of the ionic liquid’s peak to standards of known cross section (cyclohexane, carbon tetrachloride, benzene, dichloromethane, and acetonitrile). Differential and absolute cross sections were determined experimentally at wavelengths 416 nm, 487 nm, 514 nm, 532 nm and 633 nm. A-term plots were constructed with these results to obtain the coupling constant and the effective excited state energy. These parameters allowed the calculation of the differential and absolute scattering cross sections at any wavelength. This project is the first in a series of investigations to determine the electron transfer rate of ionic liquids and determine their suitability as materials in new devices.
- ItemSensors for optics-based strain, temperature and chemical sensing : a thesis presented in partial fulfilment of the requirements for the degree of Doctor of Philosophy in Physics at Massey University, Palmerston North, New Zealand(Massey University, 2015) Swanson, Adam JamesThis thesis is a study of optical sensor development with two themes. Firstly, the development of polymer coated glass optical fibre sensors for relative humidity sensing. Secondly, the development and characterisation of novel planar dye- doped polymer waveguide sensors for strain, temperature and chemical sensing. This thesis was motivated by the need to measure strain, temperature and chemi- cals in harsh conditions with high precision (including compact, high electric field or explosive environments where traditional sensors can not be used). In addi- tion, dye-doped polymer optical chips are being developed for telecommunication applications and their dependence on humidity, temperature and strain will be a key consideration. Sensor applications utilising dye-doping can achieve a greater sensitivity over traditional undoped sensors. The developed polymer coated glass optical fibre sensors were characterised with humidity calibration experiments. A polyimide based coating was found to have a humidity response of 7.2 pm/%rh corresponding to a coefficient of moisture expansion of 74 ppm/%rh. A series of modified block co-polymer coatings was investigated to identify important chemical structure features. Enhanced perfor- mance was achieved by the modification of the chemical structure of an existing commercial polyetherimide. A correlation between coating thickness and optical fibre diameter was observed where the humidity response was enhanced by using thicker coatings or smaller diameter fibres due to a fibre to coating ratio effect. The time response of the sensor’s to a humidity step change was measured. To ex- plore the response time dependencies the sensors humidity step change response a novel two-layer model was proposed. A mesh model was also utilised to calcu- late the diffusion coefficient for each coating. The time response was found to be highly dependent on coating thickness with response time increasing significantly with thickness. Novel dye-doped polymer sensors were developed by photo-bleaching waveg- uides containing Bragg gratings, with Bragg reflections observed. The sensor fabrication process was refined by modifying the waveguide dimensions and util- ising precise phase mask alignment to obtain a single-mode waveguide with a single Bragg reflection. Methods of coupling the film sensor to a single-mode fibre with a housing unit was explored and a novel method proposed and tested. The film sensors were characterised with strain, temperature and chemical sensing experiments. A strong humidity response in the range of 55 to 65 pm/%rh and the time responses to a humidity step change were measured. Strain responses in the range of 1.70 to 1.80 pm/µo were observed, exceeding that of comparable silica and PMMA sensors.