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Item Some consequences of mole draining a yellow-grey earth under pasture : a thesis presented in partial fulfilment of the requirements for the degree of Doctor of Philosophy in Soil Science at Massey University(Massey University, 1985) Horne, David JohnAlthough subsurface drainage of pasture soils is widely practiced in New Zealand there is little information available which details the likely benefits of such drainage schemes. As drainage is becoming increasingly expensive there is a need for more quantitative data on which to base assessments of the likely cost-effectiveness of proposed schemes. The effect of subsurface drainage on certain soil and plant properties was investigated at a research site on a sheep and beef farm 6 km from Palmerston North. The soil type was a yellow-grey earth, with poor drainage due to water perching on the fragipan. Of nine plots, each 0.4 ha in area, three were left undrained and six were mole drained. Three of the drained plots had conventional pipe collecting drains and the other three used major mole channels as collecting drains. The research site was grazed as part of the normal farm rotation. Data were collected in 1981 prior to the installation of drains, then from 1982 to 1984. Watertable levels were monitored in a series of four groundwater observation wells on each plot and the gravimetric water content of the top 30 mm of each plot was determined on a regular basis from soil cores. Soil temperature measurements were made at 50 mm depth on a pipe-mole and undrained plot, using thermistor thermometers, and at 100 mm depth on all the pipe-mole and undrained plots using mercury-in-glass thermometers. Pasture growth rates were measured in caged areas using a capacitance pasture meter and by mowing. Residual pasture left by the grazing animal was determined using small quadrats, the pasture meter and by visual assessment. Botanical composition was determined by point analysis and dissection of samples removed from the caged areas. Available soil nitrogen, phosphorus and sulphur in the top 75 ram of each plot, and the total levels of these three nutrients in grass and clover grown on the plots, were measured using standard procedures. Two radioactive isotopes (32P and 35S) were used simultaneously to study the plant root activity on the undrained and pipe-mole plots. Data from groundwater observation wells showed that mole drainage was very effective at lowering the watertable following heavy rain in winter or spring. There was no significant difference between water-table depth on the pipe-mole and mole-mole plots. The close proximity of the watertable to the surface on the undrained plots was reflected in high soil water content values for the top 30 mm of soil. Differences in water content of the surface soil between drained and undrained plots did not affect the levels of extractable phosphate, sulphate, ammonium or nitrate or the pH in the top 75 mm of soil. Soil temperature measurements at 50 and 100 mm depth showed that drained plots did not warm any more quickly in spring than did undrained plots. A simple mathematical analysis confirmed that the lowering of the soil heat capacity by drainage would not be expected to affect soil temperature significantly in a yellow-grey earth under pasture. There was little difference in pasture growth rates and utilisation during the very dry winter and spring of 1982, but during mob grazing in the wetter winter of 1983 utilisation was approximately 25% greater on drained than undrained plots. Subsequently, utilisation of pasture by sheep which were set stocked in spring continued to be poorer on the undrained plots, with approximately 35% more residual dry matter remaining on the undrained than on the drained plots. From the time of mob grazing in July until the end of spring both mowing and the pasture meter data showed that growth rates were approximately 30% greater on the drained plots. Point analysis at the end of spring revealed that on the undrained plots there was a 3-fold increase in the incidence of weeds, a 4-fold increase in the incidence of bare ground and a 2-fold decrease in the incidence of clover compared with the drained plots. Almost identical results were obtained from herbage dissections. There was also a decrease in the concentrations of N, P and S in the dry matter of grass and clover grown on the undrained plots compared with that grown on the drained plots. These differences were for the most part small and ephemeral. Isotope uptake studies showed that in winter drainage enabled both grass and clover roots to extract both sulphate and phosphate from a greater depth, with approximately 6% of the relative root activity occuring at 40 - 80 mm depth on the undrained plots compared with approximately 15% on the drained plots. In spring, approximately 16% of the relative root activity was at 80 - 200 mm depth on the undrained plots compared with approximately 26% on the drained plots. The benefits of drainage became apparent only after grazing on a wet soil and were probably due to the effect that drainage had on the water content and so strength of the surface soil. Drainage increased the bearing strength of the surface soil, minimizing treading damage to both the sward and the soil structure and therefore enhancing both pasture utilisation during grazing, and subsequent regrowth. A simple mathematical model was developed, which used weather data to predict the watertable levels in both drained and undrained soil. By varying certain soil properties and drainage design parameters within the model, the limiting steps in the drainage process in the Tokormaru silt loam were investigated. The model was also designed to calculate the number of days over the winter-spring period on which the surface soil would be so wet that grazing would have the adverse consequences described above. In a year of average rainfall, mole drainage reduced the number of such 'unsafe' grazing days from 69 to 10. By comparing the number of 'unsafe' grazing days for different rainfall regimes some idea of the cost-effectiveness of drainage may be ascertained.Item Potential uses of fluidised bed boiler ash as a liming material, soil conditioner and sulphur fertiliser : a thesis presented in partial fulfilment of the requirements for the degree of Doctor of Philosophy in Soil Science at Massey University(Massey University, 1996) Wang, Hailong; Wang, HailongA fluidised bed boiler ash, produced by the New Zealand Dairy Corporation (NZDC FBA) as a by-product resulting from the combined combustion of high S coal and limestone, was chemically characterised and evaluated as a potential liming material, soil conditioner and S source in some representative New Zealand soils. Chemical analysis showed that slaked NZDC FBA had a pHwater of 12.4 and CaCO3 equivalent of 51.8%. The "lime" in FBA is mainly Ca(OH)2, making it a quicker acting, more caustic material than limestone. FBA contained 6.2% S, 25.4% Ca (dry weight basis) and negligible amounts of P, K and Mg. Mineralogical analysis indicated that approximately 50% of the S in the slaked FBA is gypsum (CaSO4.2H2O) with the remainder being water insoluble ettringite (Ca6Al2(SO4)3(OH)12.26H2O). A field trial was established on a permanent dairy pasture (predominantly ryegrass (Lolium perenne) and white clover (Trifolium repens)) on peat soil, in Moanatuatua peatland, Waikato, New Zealand, to examine the effectiveness of FBA as a soil conditioner to overcome soil water repellency, a liming material and a S source. The treatments included the untreated control and three rates of FBA (1000, 6616 and 26462 kg FBA ha-1, wet weight basis), which were surface dressed onto the pasture. Three rates of lime, which had the same CaCO3 equivalent as the corresponding rates of FBA, were included for comparison. Using the molarity of ethanol droplet (MED) test, the air dried peat soil sampled in summer was classified as severely water repellent (MED > 2.2). Fatty acids were identified as the fraction most responsible for the repellent character of the peat soil. Only the high rate (26462 kg ha-1) of FBA significantly reduced water repellency of surface peat soil and increased the rate of water infiltration into the dry peat. The hydrophobic nature of the peat soil was probably modified by the high alkalinity of applied FBA, which removed or saponified fatty acids from the soil particle surface. However, normal liming and fertiliser rates (6616 kg ha-1 or less) of FBA application, as well as all the lime treatments, had negligible effect on the water repellency of the peat soil. Therefore, it is not practical to use FBA as an amendment to minimise water repellency on peat soil. The FBA treatments significantly increased pasture yield, in the field trial during eight months of the experimental period, mainly by improving herbage S nutrition status. In spring, the S concentrations in herbage from the FBA treatments were raised from a deficient level of 0.20% S (the untreated control) to 0.27 - 0.40% S. The ettringite-sulphate in FBA acted as a slow-release S fertiliser and high rates of FBA application maintained the raised S concentrations in the herbage for the eight month period. The presence of ettringite implies that application of FBA-sulphate has the potential to reduce the leaching loss of sulphate, a common problem in many New Zealand soils. In a laboratory incubation and leaching study using repacked peat soil cores, the effect of surface applied FBA and lime on base and solute movement in soil was investigated. The results indicated that FBA was an effective alternative to agricultural lime to neutralise the acidity of peat soil. Although surface-applied FBA had no significant effect on decreasing subsurface soil acidity as measured by pH change in the peat soil, the Ca2+ ions released by FBA dissolution moved down to subsurface soil much faster than those released from lime. Increased Ca2+ ion concentration in subsurface soil can alleviate the acidity constraints on pasture root growth through the antagonistic relationship between Ca2+ and H+ ions. In contrast to the lime treatment, however, FBA caused significant leaching of native soil exchangeable K+. Therefore, K fertilisers should accompany FBA application to peat soils. In order to examine the effect of topsoil incorporated FBA on the subsurface acidity in mineral soils, six acidic topsoils (0 - 100 mm) were tested for their ability to "self-lime" through sulphate sorption from gypsum treatment. Two soils, from the yellow-brown loam, or Allophanic soil (the Patua soil) and the yellow-brown earth, or Ultic soil (the Kaawa soil) groups (orders), which contrasted strongly in their reaction to gypsum treatment, were chosen for further study. Lime, FBA and Flue gas desulphurisation gypsum (FGDG) were incorporated in the top 0 - 50 mm of repacked columns of the Patua and Kaawa soils, at rates containing Ca equivalent to 5000 kg ha-1 of CaCO3. Each column was leached with 400 mm of water. After leaching, one set of the columns were sliced into sections for chemical analysis, and another set was used for growing lucerne (Medicago sativa. L) as a root bioassay. In the columns of the variable charged, allophanic Patua soil, topsoil incorporated NZDC FBA ameliorated top and subsurface soil acidity through liming and the "self-liming effect" induced by sulphate sorption, respectively. The soil solution pH of the top and subsurface layers of the Patua soil were raised to pH 6.40 and 5.35 respectively, by the FBA treatment, compared with pH 4.80 and 4.65 in the control treatment. Consequently phytotoxic labile monomeric Al concentration in soil solution of the FBA treatment was reduced to less than 0.1 µmol Al dm-3, compared with that of 8 - 64 µmol Al dm-3 in the untreated control. These changes were associated with greatly improved lucerne root growth in the subsurface of the Patua soil after FBA treatment. FGDG had a similar "self-liming effect" on subsurface of the Patua soil, but not the topsoil. Whereas FBA raised the pH of the Kaawa topsoil, no "self-liming effect" of subsurface soil by sulphate sorption was observed on the Kaawa soil, which is dominated by permanently charged clay minerals. Application of FBA and FGDG to both soils, however, caused significant leaching of native soil Mg2+ and K+. These nutrients were displaced from the exchange sites by the relatively high concentration of Ca2+ released from dissolution of gypsum. In contrast, the topsoil incorporated lime had little effect on either the subsurface soil acidity or nutrient leaching. NZDC FBA is an ideal by-product for correcting topsoil and subsurface soil acidity in yellow-brown loam (allophanic) soils, but only topsoil acidity on yellow-brown earth (Ultic) soils, dominated by clays with permanent charge. Mg and K fertiliser application would be recommended when a soil is treated with FBA or other gypsiferous materials.Item The convection dispersion equation -- not the question, the answer! : anion and cation transport through undisturbed soil columns during unsaturated flow : a thesis presented in partial fulfilment of the requirements for the degree of Doctor of Philosophy in Soil Science at Massey University(Massey University, 1997) Vogeler, Iris; Vogeler, IrisPrediction of solute movement through the unsaturated zone is important in determining the risk of groundwater contamination from both "natural" and surface applied chemicals. In order to understand better the mechanisms controlling this water-borne transport, unsaturated leaching experiments were carried out on undisturbed soil columns, about 3 litres in volume, for two contrasting soils. One was the weakly-structured Manawatu fine sandy loam, and the other the well-aggregated Ramiha silt loam. Anion transport was satisfactorily described using the convection dispersion equation (CDE), provided that anion exclusion for the Manawatu soil, and adsorption for the Ramiha soil were taken into account. At water flux densities of about 3 mm h-1, a dispersivity of about 40 mm was obtained for the Manawatu soil, and a dispersivity of about 15 mm for the Ramiha soil. The difference was probably due to the contrasting structures of the two soils. Increasing the water flux density in the Manawatu soil to about 13 mm h-1 resulted in a slightly higher dispersivity of about 60 mm. Flow interruption resulted in a subsequent drop in the effluent concentration for the Manawatu soil but not in the Ramiha soil. This suggests that the lag time for transverse molecular diffusion from "mobile" to "immobile" water domains was important in the Manawatu soil, but not in the Ramiha soil. In both soils cation transport was described satisfactorily with the CDE in conjunction with cation exchange theory, providing that only 80% of the cations replaced by 1 M ammonium acetate were assumed to be involved in exchange reactions. Column leaching experiments were also carried out using a rainfall simulator and larger columns of about 22 litres of the Manawatu soil with a short pasture on top. Solid chemical was applied to both a dry and a wet soil surface. Neither the pasture nor the initial water content had a significant effect on solute movement. Slightly higher dispersivities of about 70 mm were found. Time Domain Reflectometry (TDR) was found to be valuable for monitoring solute transport in a repacked soil under transient water flow conditions. But in undisturbed soils TDR only proved to be accurate under steady-state water flow when absolute values of solute concentration were not sought. The CDE was thus found to satisfactorily answer the question of how to describe transport of non-reactive and reactive solutes under bare soil and under short pasture. This applied during both steady-flow and transient wetting.
