Massey Research Online - Browsing by Author "Quinton JS"

Browsing by Author "Quinton JS"

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Characterisation of the Material and Mechanical Properties of Atomic Force Microscope Cantilevers with a Plan-View Trapezoidal Geometry
(MDPI (Basel, Switzerland), 2019-07-01) Slattery AD; Blanch AJ; Shearer CJ; Stapleton AJ; Goreham RV; Harmer SL; Quinton JS; Gibson CT
Cantilever devices have found applications in numerous scientific fields and instruments, including the atomic force microscope (AFM), and as sensors to detect a wide range of chemical and biological species. The mechanical properties, in particular, the spring constant of these devices is crucial when quantifying adhesive forces, material properties of surfaces, and in determining deposited mass for sensing applications. A key component in the spring constant of a cantilever is the plan-view shape. In recent years, the trapezoidal plan-view shape has become available since it offers certain advantages to fast-scanning AFM and can improve sensor performance in fluid environments. Euler beam equations relating cantilever stiffness to the cantilever dimensions and Young’s modulus have been proven useful and are used extensively to model cantilever mechanical behaviour and calibrate the spring constant. In this work, we derive a simple correction factor to the Euler beam equation for a beam-shaped cantilever that is applicable to any cantilever with a trapezoidal plan-view shape. This correction factor is based upon previous analytical work and simplifies the application of the previous researchers formula. A correction factor to the spring constant of an AFM cantilever is also required to calculate the torque produced by the tip when it contacts the sample surface, which is also dependent on the plan-view shape. In this work, we also derive a simple expression for the torque for triangular plan-view shaped cantilevers and show that for the current generation of trapezoidal plan-view shaped AFM cantilevers, this will be a good approximation. We shall apply both these correction factors to determine Young’s modulus for a range of trapezoidal-shaped AFM cantilevers, which are specially designed for fast-scanning. These types of AFM probes are much smaller in size when compared to standard AFM probes. In the process of analysing the mechanical properties of these cantilevers, important insights are also gained into their spring constant calibration and dimensional factors that contribute to the variability in their spring constant.
Characterization of Al-12Si Thin-Wall Properties Fabricated with Laser Direct Energy Deposition
(MDPI (Basel, Switzerland), 2023-08-24) Rumman R; Manjaiah M; Touzé S; Sims RA; Hascoët J-Y; Quinton JS; Narayanan JA; Kaji F; Pathak S
Additive manufacturing is an emerging process that is used to manufacture industrial parts layer by layer and can produce a wide range of geometries for various applications. AM parts are adopted for aerospace, automobiles, antennas, gyroscopes, and waveguides in electronics. However, there are several challenges existing in manufacturing Al components using the AM process, and their mechanical and microstructural properties are not yet fully validated. In the present study, a gas-atomised powder of a eutectic Al-12Si alloy was used as feedstock for the Laser Direct Energy Deposition (LDED) process. A SEM analysis of Al-12Si powder used for processing illustrated that particles possess appropriate morphology for LDED. A numerical control system was used to actuate the deposition head towards printing positions. The deposited samples revealed the presence of Al-rich and Al-Si eutectic regions. The porosity content in the samples was found to be around 2.6%. Surface profile roughness measurements and a microstructural analysis of the samples were also performed to assess the fabricated sample in terms of the roughness, porosity, and distribution of Al and Al/Si eutectic phases. The tensile properties of fabricated thin walls were better compared to casted Al alloys due to the uniform distribution of Si in each layer. Micro-hardness tests on the deposited samples showed a hardness of 95 HV, which is equivalent to casted and powder bed fusion melting samples. The gas atomised Al-12Si powders are highly reflective to a laser and also quick oxidation takes place, which causes defects, porosity, and the balling effect during fabrication. The results can be used as a base guide for the further fabrication of aerospace component design with high structural integrity.
Improved Application of Carbon Nanotube Atomic Force Microscopy Probes Using PeakForce Tapping Mode
(MDPI (Basel, Switzerland), 2018-10) Slattery AD; Shearer CJ; Shapter JG; Blanch AJ; Quinton JS; Gibson CT
In this work PeakForce tapping (PFT) imaging was demonstrated with carbon nanotube atomic force microscopy (CNT-AFM) probes; this imaging mode shows great promise for providing simple, stable imaging with CNT-AFM probes, which can be difficult to apply. The PFT mode is used with CNT-AFM probes to demonstrate high resolution imaging on samples with features in the nanometre range, including a Nioprobe calibration sample and gold nanoparticles on silicon, in order to demonstrate the modes imaging effectiveness, and to also aid in determining the diameter of very thin CNT-AFM probes. In addition to stable operation, the PFT mode is shown to eliminate "ringing" artefacts that often affect CNT-AFM probes in tapping mode near steep vertical step edges. This will allow for the characterization of high aspect ratio structures using CNT-AFM probes, an exercise which has previously been challenging with the standard tapping mode.
Scanning Auger Microscopy Studies of Silane Films Grown on Plasma-Modified HOPG Surfaces
(MDPI (Basel, Switzerland), 2019-02-12) Taylor JK; Wiese JR; Harmer SL; Quinton JS
The growth of silane films on plasma oxidized highly oriented pyrolytic graphite (HOPG) surfaces has been studied using wet chemical deposition of propyltrimethoxysilane (PTMS) and propyldimethylmethoxysilane (PDMMS). Scanning Auger microscopy (SAM) and X-ray photoelectron spectroscopy (XPS) were used to investigate the chemical composition and morphology of the silane films. The effects of several deposition parameters were examined, including the necessity of oxidation of the HOPG surface, addition of water with the silane, and rinsing before curing. The optimal conditions needed to create a complete uniform film differ for the two silanes due to differences in their structures. Both silanes require an oxidized HOPG surface for a film to grow, the addition of water with PTMS results in a thicker film, while the addition of water with PDMMS decreases the film growth. Rinsing of both samples before curing removes physisorbed species, leaving only the covalently bonded film on the surface.
Sub-micron moulding topological mass transport regimes in angled vortex fluidic flow
(The Royal Society of Chemistry, 2021-06-07) Alharbi TMD; Jellicoe M; Luo X; Vimalanathan K; Alsulami IK; Al Harbi BS; Igder A; Alrashaidi FAJ; Chen X; Stubbs KA; Chalker JM; Zhang W; Boulos RA; Jones DB; Quinton JS; Raston CL
Shear stress in dynamic thin films, as in vortex fluidics, can be harnessed for generating non-equilibrium conditions, but the nature of the fluid flow is not understood. A rapidly rotating inclined tube in the vortex fluidic device (VFD) imparts shear stress (mechanical energy) into a thin film of liquid, depending on the physical characteristics of the liquid and rotational speed, ω, tilt angle, θ, and diameter of the tube. Through understanding that the fluid exhibits resonance behaviours from the confining boundaries of the glass surface and the meniscus that determines the liquid film thickness, we have established specific topological mass transport regimes. These topologies have been established through materials processing, as spinning top flow normal to the surface of the tube, double-helical flow across the thin film, and spicular flow, a transitional region where both effects contribute. The manifestation of mass transport patterns within the film have been observed by monitoring the mixing time, temperature profile, and film thickness against increasing rotational speed, ω. In addition, these flow patterns have unique signatures that enable the morphology of nanomaterials processed in the VFD to be predicted, for example in reversible scrolling and crumbling graphene oxide sheets. Shear-stress induced recrystallisation, crystallisation and polymerisation, at different rotational speeds, provide moulds of high-shear topologies, as 'positive' and 'negative' spicular flow behaviour. 'Molecular drilling' of holes in a thin film of polysulfone demonstrate spatial arrangement of double-helices. The grand sum of the different behavioural regimes is a general fluid flow model that accounts for all processing in the VFD at an optimal tilt angle of 45°, and provides a new concept in the fabrication of novel nanomaterials and controlling the organisation of matter.
Surface Chemical Characterisation of Pyrite Exposed to Acidithiobacillus ferrooxidans and Associated Extracellular Polymeric Substances
(MDPI (Basel, Switzerland), 2018-04-01) La Vars SM; Newton K; Quinton JS; Cheng P-Y; Wei D-H; Chan Y-L; Harmer SL
A. ferrooxidans and their metabolic products have previously been explored as a viable alternative depressant of pyrite for froth flotation; however, the mechanism by which separation is achieved is not completely understood. Scanning electron microscopy (SEM), photoemission electron microscopy (PEEM), time-of-flight secondary ion mass spectrometry (ToF-SIMS) and captive bubble contact angle measurements have been used to examine the surface physicochemical properties of pyrite upon exposure to A. ferrooxidans grown in HH medium at pH 1.8. C K-edge near edge X-ray absorption fine structure (NEXAFS) spectra collected from PEEM images indicate hydrophilic lipids, fatty acids and biopolymers are formed at the mineral surface during early exposure. After 168 h, the spectra indicate a shift towards protein and DNA, corresponding to an increase in cell population and biofilm formation on the surface, as observed by SEM. The Fe L-edge NEXAFS show gradual oxidation of the mineral surface from Fe(II) sulfide to Fe(III) oxyhydroxides. The oxidation of the iron species at the pyrite surface is accelerated in the presence of A. ferrooxidans and extracellular polymeric substances (EPS) as compared to HH medium controls. The surface chemical changes induced by the interaction with A. ferrooxidans show a significant decrease in surface hydrophobicity within the first 2 h of exposure. The implications of these findings are the potential use of EPS produced during early attachment of A. ferrooxidans, as a depressant for bioflotation.
The Role of Physisorption and Chemisorption in the Oscillatory Adsorption of Organosilanes on Aluminium Oxide
(MDPI (Basel, Switzerland), 2019-03) Sims RA; Harmer SL; Quinton JS
The effect of physisorbed and chemisorbed species on the time-dependent self-assembly mechanism of organosilane films has been investigated on aluminium oxide using X-ray Photoelectron Spectroscopy. The role of physisorbed species was determined through their removal using a simple rinsing procedure while monitoring film substrate coverage. Removing physisorbed species from Propyldimethylmethoxysilane films, shown to follow a Langmuir-type adsorption profile, reduces the substrate coverage initially but quickly results in coverages equivalent to films that did not undergo a rinsing procedure. This indicates that all Propyldimethylmethoxysilane molecules are covalently bound to the substrate following 15 s of film growth. Removing physisorbed species from films, which have been shown to follow an oscillatory adsorption profile, Propyltrimethoxysilane and Propylmethyldimethoxysilane, reveal the persistence of these oscillations despite a reduction in silane substrate coverage. These results not only confirm the presence of two thermodynamically favourable phases in the condensation equilibrium reaction as physisorbed and chemisorbed species, but also indicate that the desorption of species during film growth involves both states of chemical binding.
The Vice Chancellor in Australian Universities: Understanding Leadership Beyond ‘Bad Apples’ and ‘Unicorns’
(30/03/2022) Quinton JS; Brabazon TM
Leadership in Australian higher education has confronted crises, threats, restructures, and embarrassment. From sexual harassment claims to nepotism, regulatory authorities have investigated individual Vice Chancellors and their behaviour. Such crises reveal the consequences of decision making and appointment processes. While COVID-19 demonstrated the institutional reliance on international students to ensure financial security, these weaknesses existed long before the pandemic. Through this troubled time, are there patterns or priorities that ‘create’ a Vice Chancellorship? How do researchers understand leadership in our universities, beyond ‘a few bad apples’ – to describe the excesses and improprieties – or the ‘unicorns’ that have trotted the golden path to success? This article arches beyond the individual cases that become tabloidized headlines. Instead, we probe if there are shared characteristics among Vice Chancellors, evaluating how career progression emerges in the higher education sector. This article also assesses the consequences of this leadership pathway on universities, particularly for building a post-pandemic future.
Vortex fluidic induced mass transfer across immiscible phases
(The Royal Society of Chemistry, 2022-03-28) Jellicoe M; Igder A; Chuah C; Jones DB; Luo X; Stubbs KA; Crawley EM; Pye SJ; Joseph N; Vimalananthan K; Gardner Z; Harvey DP; Chen X; Salvemini F; He S; Zhang W; Chalker JM; Quinton JS; Tang Y; Raston CL
Mixing immiscible liquids typically requires the use of auxiliary substances including phase transfer catalysts, microgels, surfactants, complex polymers and nano-particles and/or micromixers. Centrifugally separated immiscible liquids of different densities in a 45° tilted rotating tube offer scope for avoiding their use. Micron to submicron size topological flow regimes in the thin films induce high inter-phase mass transfer depending on the nature of the two liquids. A hemispherical base tube creates a Coriolis force as a ‘spinning top’ (ST) topological fluid flow in the less dense liquid which penetrates the denser layer of liquid, delivering liquid from the upper layer through the lower layer to the surface of the tube with the thickness of the layers determined using neutron imaging. Similarly, double helical (DH) topological flow in the less dense liquid, arising from Faraday wave eddy currents twisted by Coriolis forces, impact through the less dense liquid onto the surface of the tube. The lateral dimensions of these topological flows have been determined using ‘molecular drilling’ impacting on a thin layer of polysulfone on the surface of the tube and self-assembly of nanoparticles at the interface of the two liquids. At high rotation speeds, DH flow also occurs in the denser layer, with a critical rotational speed reached resulting in rapid phase demixing of preformed emulsions of two immiscible liquids. ST flow is perturbed relative to double helical flow by changing the shape of the base of the tube while maintaining high mass transfer between phases as demonstrated by circumventing the need for phase transfer catalysts. The findings presented here have implications for overcoming mass transfer limitations at interfaces of liquids, and provide new methods for extractions and separation science, and avoiding the formation of emulsions.

Browsing by Author "Quinton JS"

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