Salicylaldoxime derivatives for new magnetic materials : a thesis presented in partial fulfilment of the requirements for the degree of Master of Science in Chemistry at Massey University, Manawatu, New Zealand

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dc.contributor.authorWoodhouse, Sidney
dc.date.accessioned2019-11-29T02:42:40Z
dc.date.available2019-11-29T02:42:40Z
dc.date.issued2019
dc.description.abstractSalicylaldoxime (H₂Sao) is an appealing unit for metal ion coordination, specifically that of transition metal (3d) ions. During this research, four ligands were synthesised, of which two were previously unknown (L2 and L3). These ligands differed by the secondary amine added to the simple H₂Sao molecule. These H₂Sao derived ligands were complexed with a variety of 3d ions, resulting in three distinct topologies: mononuclear, triangular, and defective dicubane. The nine new complexes (C1-C9) synthesised were all structurally characterised, with Mössbauer spectroscopy performed on the iron complexes, and magnetic characterisation performed on complexes C1-C6, C8-C9. Analysis of the synthesised complexes has led to new insights into magnetostructural correlations and new pathways to unique ligand designs.en_US
dc.identifier.urihttp://hdl.handle.net/10179/15066
dc.language.isoenen_US
dc.publisherMassey Universityen_US
dc.rightsThe Authoren_US
dc.subjectMetal clustersen_US
dc.subjectMagnetic propertiesen_US
dc.subjectTransition metal compoundsen_US
dc.subjectSpectraen_US
dc.subjectLigandsen_US
dc.subjectIronen_US
dc.titleSalicylaldoxime derivatives for new magnetic materials : a thesis presented in partial fulfilment of the requirements for the degree of Master of Science in Chemistry at Massey University, Manawatu, New Zealanden_US
dc.typeThesisen_US
massey.contributor.authorWoodhouse, Sidney
thesis.degree.disciplineChemistryen_US
thesis.degree.levelMastersen_US
thesis.degree.nameMaster of Science (MSc)en_US
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