The concise synthesis and resolution of planar chiral [2.2]paracyclophane oxazolines by C-H activation
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Date
2022-03-17
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Royal Society of Chemistry
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(c) 2022 The Author/s
CC BY-NC 3.0
CC BY-NC 3.0
Abstract
Planar chiral [2.2]paracyclophanes are resolved through the direct C-H arylation of enantiopure oxazolines, providing a convenient route to ligands and chiral materials. Preliminary results show that hydrolysis followed by decarboxylative phosphorylation leads to enantiopure [2.2]paracyclophane derivatives that are otherwise challenging to prepare.
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Tewari S, Mungalpara MN, Patel S, Rowlands GJ. (2022). The concise synthesis and resolution of planar chiral [2.2]paracyclophane oxazolines by C-H activation.. RSC Adv. 12. 14. (pp. 8588-8591).