Thioether and related ligand complexes of copper : a thesis presented in partial fulfilment of the requirements for the degree of Master of Science

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dc.contributor.authorPalmer, Kevin Charles
dc.date.accessioned2018-10-09T21:42:46Z
dc.date.available2018-10-09T21:42:46Z
dc.date.issued1975
dc.description.abstractThe dithioethers 2,5-dithiahexane (DTH) and 3,6-dithiaoctane (DTO) form the following stable copper (II) complexes; Cu(S͡S)X₂ where S͡S=DTH or DTO and X=Cl or Br, and also Cu(DTH)₂(BF₄)₂ The complexes Cu(DTO)₂(BF₄)₂ and Cu(DTO)(NO₃)₂.H₂O decomposed over a short period of time. The following copper (I) complexes were also prepared: [CuX)₂DTO]n where X=Cl or Br, Cu(DTO)I, Cu(DTH)Cl, [Cu(DTH)X]n where X=Br or I, [Cu(DTO)SCN]n and Cu(DTO)₂ BF₄. The complexes were characterised using infra-red spectroscopy, visible-U.V. spectroscopy, Raman spectroscopy, x-ray powder photography, conductivity and molecular weight measurements, and proton nuclear magnetic resonance spectroscopy. Some reactions were also carried out by displacement of the dithioethers with a variety of monodentate and bidentate ligands, e.g. pyridine, ethylenediamine, trimethylphosphine sulphide, sodium dimethyldithiophosphinate dihydrate, and triphenylphosphine which also forms an adduct with Cu(DTH) Cl to give Cu(DTH) (Ø₃P) Cl.en_US
dc.identifier.urihttp://hdl.handle.net/10179/13830
dc.language.isoenen_US
dc.publisherMassey Universityen_US
dc.rightsThe Authoren_US
dc.subjectCopperen_US
dc.subjectCoordination compoundsen_US
dc.subjectLigandsen_US
dc.titleThioether and related ligand complexes of copper : a thesis presented in partial fulfilment of the requirements for the degree of Master of Scienceen_US
dc.typeThesisen_US
massey.contributor.authorPalmer, Kevin Charles
thesis.degree.grantorMassey Universityen_US
thesis.degree.levelMastersen_US
thesis.degree.nameMaster of Science (M. Sc.)en_US
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