Lanthanide-Based Langmuir–Blodgett Multilayers: Multi-Emissive, Temperature-Dependent Thin Films

dc.citation.issue4
dc.citation.volume4
dc.contributor.authorO’Neil AT
dc.contributor.authorKitchen JA
dc.contributor.editorRice C
dc.date.accessioned2023-12-15T01:56:37Z
dc.date.accessioned2024-07-25T06:34:37Z
dc.date.available2022-11-07
dc.date.available2023-12-15T01:56:37Z
dc.date.available2024-07-25T06:34:37Z
dc.date.issued2022-12
dc.description.abstractMulti-emissive compounds have attracted significant attention from the research community owing to the wide array of potential application areas. However, to move towards application, such systems should be readily immobilized by solution-based methods to form soft materials such as gels and films. Herein we report the use of Langmuir–Blodgett (LB) deposition to easily immobilize luminescent lanthanide-based amphiphilic solids into multi-emissive ultrathin LB films, by multilayering different luminescent amphiphiles. Utilizing this technique, we have reliably fabricated dual- and triple-emissive films where the overall emission from the film is tuned. Furthermore, we have demonstrated that these multi-emissive films are temperature-dependent, with emission profiles significantly altering from 294 to 340 K, resulting in colour changes and potential application as ultrathin, contactless ratiometric thermometer coatings.
dc.description.confidentialfalse
dc.edition.editionDecember 2022
dc.format.pagination1457-1465
dc.identifier.citationO’Neil AT, Kitchen JA. (2022). Lanthanide-Based Langmuir–Blodgett Multilayers: Multi-Emissive, Temperature-Dependent Thin Films. Chemistry (Switzerland). 4. 4. (pp. 1457-1465).
dc.identifier.doi10.3390/chemistry4040096
dc.identifier.eissn2624-8549
dc.identifier.elements-typejournal-article
dc.identifier.urihttps://mro.massey.ac.nz/handle/10179/70449
dc.languageEnglish
dc.publisherMDPI (Basel, Switzerland)
dc.publisher.urihttps://www.mdpi.com/2624-8549/4/4/96
dc.relation.isPartOfChemistry (Switzerland)
dc.rights(c) The author/sen
dc.rights.licenseCC BY 4.0en
dc.rights.urihttps://creativecommons.org/licenses/by/4.0/en
dc.subjectlanthanides
dc.subjectsupramolecular materials
dc.subjectLangmuir–Blodgett films
dc.subjectmulti-emissive materials
dc.subjectcolour-tunable materials
dc.subjecttemperature sensors
dc.subjectratiometric thermometer
dc.titleLanthanide-Based Langmuir–Blodgett Multilayers: Multi-Emissive, Temperature-Dependent Thin Films
dc.typeJournal article
pubs.elements-id458955
pubs.organisational-groupOther
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