[Fe(µ2-OH)6]3- Linked Fe3O Triads: Mössbauer Evidence for Trigonal µ3-O2- or µ3-OH- Groups in Bridged versus Unbridged Complexes.

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dc.citation.issue13
dc.citation.volume29
dc.contributor.authorDe Silva DNT
dc.contributor.authorDais TN
dc.contributor.authorJameson GB
dc.contributor.authorDavies CG
dc.contributor.authorJameson GNL
dc.contributor.authorPlieger PG
dc.contributor.editorNiclós-Gutiérrez J
dc.contributor.editorBarceló-Oliver M
dc.coverage.spatialSwitzerland
dc.date.accessioned2024-07-17T23:38:19Z
dc.date.available2024-07-17T23:38:19Z
dc.date.issued2024-07-07
dc.description.abstractThe syntheses, coordination chemistry, and Mössbauer spectroscopy of hepta-iron(III) complexes using derivatised salicylaldoxime ligands from two categories; namely, 'single-headed' (H2L) and 'double-headed' (H4L) salicylaldoximes are described. All compounds presented here share a [Fe3-µ3-O] core in which the iron(III) ions are µ3-hydroxo-bridged in the complex C1 and µ3-oxo-bridged in C2 and C3. Each compound consists of 2 × [Fe3-µ3-O] triads that are linked via a central [Fe(µ2-OH)6]3- ion. In addition to the charge balance and microanalytical evidence, Mössbauer measurements support the fact that the triads in C1 are µ3-OH bridged and are µ3-O bridged in C2 and C3.
dc.description.confidentialfalse
dc.edition.edition2024
dc.identifier.author-urlhttps://www.ncbi.nlm.nih.gov/pubmed/38999170
dc.identifier.citationDe Silva DNT, Dais TN, Jameson GB, Davies CG, Jameson GNL, Plieger PG. (2024). [Fe(µ2-OH)6]3- Linked Fe3O Triads: Mössbauer Evidence for Trigonal µ3-O2- or µ3-OH- Groups in Bridged versus Unbridged Complexes.. Molecules. 29. 13.
dc.identifier.doi10.3390/molecules29133218
dc.identifier.eissn1420-3049
dc.identifier.elements-typejournal-article
dc.identifier.number3218
dc.identifier.piimolecules29133218
dc.identifier.urihttps://mro.massey.ac.nz/handle/10179/70219
dc.languageeng
dc.publisherMDPI (Basel, Switzerland)
dc.publisher.urihttps://www.mdpi.com/1420-3049/29/13/3218
dc.relation.isPartOfMolecules
dc.rights(c) 2024 The Author/s
dc.rightsCC BY 4.0
dc.rights.urihttps://creativecommons.org/licenses/by/4.0/
dc.subjectMössbauer
dc.subjectcoordination chemistry
dc.subjectiron cluster
dc.title[Fe(µ2-OH)6]3- Linked Fe3O Triads: Mössbauer Evidence for Trigonal µ3-O2- or µ3-OH- Groups in Bridged versus Unbridged Complexes.
dc.typeJournal article
pubs.elements-id489685
pubs.organisational-groupOther
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