Partial Polymer Blend for Fused Filament Fabrication with High Thermal Stability

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dc.citation.issue19
dc.citation.volume13
dc.contributor.authorHarris M
dc.contributor.authorPotgieter J
dc.contributor.authorMohsin H
dc.contributor.authorRay S
dc.contributor.authorChen JQ
dc.contributor.authorArif K
dc.date.available2021-10
dc.date.available2021-09-27
dc.date.issued30/09/2021
dc.description.abstractThe materials for large scale fused filament fabrication (FFF) are not yet designed to resist thermal degradation. This research presents a novel polymer blend of polylactic acid with polypropylene for FFF, purposefully designed with minimum feasible chemical grafting and overwhelming physical interlocking to sustain thermal degradation. Multi-level general full factorial ANOVA is performed for the analysis of thermal effects. The statistical results are further investigated and validated using different thermo-chemical and visual techniques. For example, Fourier transform infrared spectroscopy (FTIR) analyzes the effects of blending and degradation on intermolecular interactions. Differential scanning calorimetry (DSC) investigates the nature of blending (grafting or interlocking) and effects of degradation on thermal properties. Thermogravimetric analysis (TGA) validates the extent of chemical grafting and physical interlocking detected in FTIR and DSC. Scanning electron microscopy (SEM) is used to analyze the morphology and phase separation. The novel approach of overwhelmed physical interlocking and minimum chemical grafting for manufacturing 3D printing blends results in high structural stability (mechanical and intermolecular) against thermal degradation as compared to neat PLA.
dc.description.publication-statusPublished
dc.identifierhttp://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000710231100001&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=c5bb3b2499afac691c2e3c1a83ef6fef
dc.identifierARTN 3353
dc.identifier.citationPOLYMERS, 2021, 13 (19)
dc.identifier.doi10.3390/polym13193353
dc.identifier.eissn2073-4360
dc.identifier.elements-id448690
dc.identifier.harvestedMassey_Dark
dc.identifier.urihttps://hdl.handle.net/10179/16638
dc.publisherMDPI AG
dc.relation.isPartOfPOLYMERS
dc.subjectfused deposition modeling
dc.subjectpolypropylene
dc.subjectpolylactic acid
dc.subjectthermal aging
dc.subjectdegradation
dc.subjectpellet printing
dc.subject.anzsrc03 Chemical Sciences
dc.subject.anzsrc09 Engineering
dc.titlePartial Polymer Blend for Fused Filament Fabrication with High Thermal Stability
dc.typeJournal article
pubs.notesNot known
pubs.organisational-group/Massey University
pubs.organisational-group/Massey University/College of Sciences
pubs.organisational-group/Massey University/College of Sciences/School of Agriculture & Environment
pubs.organisational-group/Massey University/College of Sciences/School of Agriculture & Environment/Agritech
pubs.organisational-group/Massey University/College of Sciences/School of Food and Advanced Technology
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