Journal Articles
Permanent URI for this collectionhttps://mro.massey.ac.nz/handle/10179/7915
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Item How Reproducible are Surface Areas Calculated from the BET Equation?(Wiley-VCH GmbH, 2022-05-23) Osterrieth JWM; Rampersad J; Madden D; Rampal N; Skoric L; Connolly B; Allendorf MD; Stavila V; Snider JL; Ameloot R; Marreiros J; Ania C; Azevedo D; Vilarrasa-Garcia E; Santos BF; Bu X-H; Chang Z; Bunzen H; Champness NR; Griffin SL; Chen B; Lin R-B; Coasne B; Cohen S; Moreton JC; Colón YJ; Chen L; Clowes R; Coudert F-X; Cui Y; Hou B; D'Alessandro DM; Doheny PW; Dincă M; Sun C; Doonan C; Huxley MT; Evans JD; Falcaro P; Ricco R; Farha O; Idrees KB; Islamoglu T; Feng P; Yang H; Forgan RS; Bara D; Furukawa S; Sanchez E; Gascon J; Telalović S; Ghosh SK; Mukherjee S; Hill MR; Sadiq MM; Horcajada P; Salcedo-Abraira P; Kaneko K; Kukobat R; Kenvin J; Keskin S; Kitagawa S; Otake K-I; Lively RP; DeWitt SJA; Llewellyn P; Lotsch BV; Emmerling ST; Pütz AM; Martí-Gastaldo C; Padial NM; García-Martínez J; Linares N; Maspoch D; Suárez Del Pino JA; Moghadam P; Oktavian R; Morris RE; Wheatley PS; Navarro J; Petit C; Danaci D; Rosseinsky MJ; Katsoulidis AP; Schröder M; Han X; Yang S; Serre C; Mouchaham G; Sholl DS; Thyagarajan R; Siderius D; Snurr RQ; Goncalves RB; Telfer S; Lee SJ; Ting VP; Rowlandson JL; Uemura T; Iiyuka T; van der Veen MA; Rega D; Van Speybroeck V; Rogge SMJ; Lamaire A; Walton KS; Bingel LW; Wuttke S; Andreo J; Yaghi O; Zhang B; Yavuz CT; Nguyen TS; Zamora F; Montoro C; Zhou H; Kirchon A; Fairen-Jimenez DPorosity and surface area analysis play a prominent role in modern materials science. At the heart of this sits the Brunauer-Emmett-Teller (BET) theory, which has been a remarkably successful contribution to the field of materials science. The BET method was developed in the 1930s for open surfaces but is now the most widely used metric for the estimation of surface areas of micro- and mesoporous materials. Despite its widespread use, the calculation of BET surface areas causes a spread in reported areas, resulting in reproducibility problems in both academia and industry. To prove this, for this analysis, 18 already-measured raw adsorption isotherms were provided to sixty-one labs, who were asked to calculate the corresponding BET areas. This round-robin exercise resulted in a wide range of values. Here, the reproducibility of BET area determination from identical isotherms is demonstrated to be a largely ignored issue, raising critical concerns over the reliability of reported BET areas. To solve this major issue, a new computational approach to accurately and systematically determine the BET area of nanoporous materials is developed. The software, called "BET surface identification" (BETSI), expands on the well-known Rouquerol criteria and makes an unambiguous BET area assignment possible.Item Body appreciation around the world: Measurement invariance of the Body Appreciation Scale-2 (BAS-2) across 65 nations, 40 languages, gender identities, and age.(Elsevier B.V., 2023-08-13) Swami V; Tran US; Stieger S; Aavik T; Ranjbar HA; Adebayo SO; Afhami R; Ahmed O; Aimé A; Akel M; Halbusi HA; Alexias G; Ali KF; Alp-Dal N; Alsalhani AB; Álvares-Solas S; Amaral ACS; Andrianto S; Aspden T; Argyrides M; Aruta JJBR; Atkin S; Ayandele O; Baceviciene M; Bahbouh R; Ballesio A; Barron D; Bellard A; Bender SS; Beydağ KD; Birovljević G; Blackburn M-È; Borja-Alvarez T; Borowiec J; Bozogáňová M; Bratland-Sanda S; Browning MHEM; Brytek-Matera A; Burakova M; Çakır-Koçak Y; Camacho P; Camilleri VE; Cazzato V; Cerea S; Chaiwutikornwanich A; Chaleeraktrakoon T; Chambers T; Chen Q-W; Chen X; Chien C-L; Chobthamkit P; Choompunuch B; Compte EJ; Corrigan J; Cosmas G; Cowden RG; Czepczor-Bernat K; Czub M; da Silva WR; Dadfar M; Dalley SE; Dany L; Datu JAD; Berbert de Carvalho PH; Coelho GLDH; De Jesus AOS; Debbabi SH; Dhakal S; Di Bernardo F; Dimitrova DD; Dion J; Dixson B; Donofrio SM; Drysch M; Du H; Dzhambov AM; El-Jor C; Enea V; Eskin M; Farbod F; Farrugia L; Fian L; Fisher ML; Folwarczny M; Frederick DA; Fuller-Tyszkiewicz M; Furnham A; García AA; Geller S; Ghisi M; Ghorbani A; Martinez MAG; Gradidge S; Graf S; Grano C; Gyene G; Hallit S; Hamdan M; Handelzalts JE; Hanel PHP; Hawks SR; Hekmati I; Helmy M; Hill T; Hina F; Holenweger G; Hřebíčková M; Ijabadeniyi OA; Imam A; İnce B; Irrazabal N; Jankauskiene R; Jiang D-Y; Jiménez-Borja M; Jiménez-Borja V; Johnson EM; Jovanović V; Jović M; Jović M; Junqueira ACP; Kahle L-M; Kantanista A; Karakiraz A; Karkin AN; Kasten E; Khatib S; Khieowan N; Kimong PJ; Kiropoulos L; Knittel J; Kohli N; Koprivnik M; Kospakov A; Król-Zielińska M; Krug I; Kuan G; Kueh YC; Kujan O; Kukić M; Kumar S; Kumar V; Lamba N; Lauri MA; Laus MF; LeBlanc LA; Lee HJ; Lipowska M; Lipowski M; Lombardo C; Lukács A; Maïano C; Malik S; Manjary M; Baldó LM; Martinez-Banfi M; Massar K; Matera C; McAnirlin O; Mebarak MR; Mechri A; Meireles JFF; Mesko N; Mills J; Miyairi M; Modi R; Modrzejewska A; Modrzejewska J; Mulgrew KE; Myers TA; Namatame H; Nassani MZ; Nerini A; Neto F; Neto J; Neves AN; Ng S-K; Nithiya D; O J; Obeid S; Oda-Montecinos C; Olapegba PO; Olonisakin TT; Omar SS; Örlygsdóttir B; Özsoy E; Otterbring T; Pahl S; Panasiti MS; Park Y; Patwary MM; Pethö T; Petrova N; Pietschnig J; Pourmahmoud S; Prabhu VG; Poštuvan V; Prokop P; Ramseyer Winter VL; Razmus M; Ru T; Rupar M; Sahlan RN; Hassan MS; Šalov A; Sapkota S; Sarfo JO; Sawamiya Y; Schaefer K; Schulte-Mecklenbeck M; Seekis V; Selvi K; Sharifi M; Shrivastava A; Siddique RF; Sigurdsson V; Silkane V; Šimunić A; Singh G; Slezáčková A; Sundgot-Borgen C; Ten Hoor G; Tevichapong P; Tipandjan A; Todd J; Togas C; Tonini F; Tovar-Castro JC; Trangsrud LKJ; Tripathi P; Tudorel O; Tylka TL; Uyzbayeva A; Vally Z; Vanags E; Vega LD; Vicente-Arruebarrena A; Vidal-Mollón J; Vilar R; Villegas H; Vintilă M; Wallner C; White MP; Whitebridge S; Windhager S; Wong KY; Yau EK; Yamamiya Y; Yeung VWL; Zanetti MC; Zawisza M; Zeeni N; Zvaríková M; Voracek MThe Body Appreciation Scale-2 (BAS-2) is a widely used measure of a core facet of the positive body image construct. However, extant research concerning measurement invariance of the BAS-2 across a large number of nations remains limited. Here, we utilised the Body Image in Nature (BINS) dataset - with data collected between 2020 and 2022 - to assess measurement invariance of the BAS-2 across 65 nations, 40 languages, gender identities, and age groups. Multi-group confirmatory factor analysis indicated that full scalar invariance was upheld across all nations, languages, gender identities, and age groups, suggesting that the unidimensional BAS-2 model has widespread applicability. There were large differences across nations and languages in latent body appreciation, while differences across gender identities and age groups were negligible-to-small. Additionally, greater body appreciation was significantly associated with higher life satisfaction, being single (versus being married or in a committed relationship), and greater rurality (versus urbanicity). Across a subset of nations where nation-level data were available, greater body appreciation was also significantly associated with greater cultural distance from the United States and greater relative income inequality. These findings suggest that the BAS-2 likely captures a near-universal conceptualisation of the body appreciation construct, which should facilitate further cross-cultural research.Item Development and validation of an LC-MS/MS method for the quantification of oral-sugar probes in plasma to test small intestinal permeability and absorptive capacity in the domestic cat (Felis catus)(Elsevier BV, 2024-07-15) Patterson K; Fraser K; Bernstein D; Bermingham EN; Weidgraaf K; Kate Shoveller A; Thomas DA novel method for quantifying the concentration of lactulose, rhamnose, xylose, and 3-O-methylglucose (3-OMG) in cat plasma using liquid chromatography-mass spectrometry (LC-MS) was developed. Domestic male cats (n = 13) were orally dosed with a solution containing the four sugars to test the permeability and absorptive capacity of their intestinal barrier. Plasma samples were taken 3 h later and were prepared with acetonitrile (ACN), dried under N2, and reconstituted in 90 % ACN with 1 mM ammonium formate. Stable isotope labelled 13C standards for each analyte were used as internal standards. Chromatographic separation was conducted using a Phenomenex Luna NH2 column with a gradient elution system of deionized water and 90 % ACN with 1 mM ammonium formate at 300 µL/min for 13 min total analysis time. Recovery trials were conducted in triplicate over three days with RSD values (%) for each day ranging from 1.2 to 1.4 for lactulose, 5.4 - 6.0 for rhamnose, 3.3 - 5.5 for xylose, and 2.6 - 5.6 for 3-OMG. Inter-day variations for each analyte were not different (p > 0.05). Limit of detection and quantification were 0.2 and 0.7 µg/mL for lactulose, 0.8 and 2.4 µg/mL for rhamnose, 0.6 and 1.8 µg/mL for xylose, and 0.3 and 1.1 µg/mL for 3-OMG, respectively. Plasma sugar concentrations recovered from cats were above the limit of quantification and below the highest calibration standard, validating the use of this method to test intestinal permeability and absorptive capacity in cats.Item Translation, adaptation, and cross-cultural validation into Brazilian portuguese of the hearing protection assessment questionnaire (HPA)(Sociedade Brasileira de Fonoaudiologia, 2023-05-01) Bramati L; Gonçalves CGDO; Marques JM; Reddy R; Welch D; Lacerda ABDMPURPOSE: The aim of the present study is to translate, adapt, and cross-culturally validate the Brazilian Portuguese version of the questionnaire Hearing Protection Assessment Questionnaire (HPA). METHODS: The original instrument, developed in English, seeks to assess barriers and supports related to the use of hearing protection devices (HPD), as well as workers' knowledge, habits and attitudes towards occupational noise. The translation, adaptation, and cross-cultural validation of the questionnaire consisted of five steps: Translation of the questionnaire from English to Portuguese; 2) Reverse translation from Portuguese to English; 3) Analysis of the instrument by three experts in the field; 4) Pre-test of the questionnaire with ten workers; 5) Application of the instrument to 509 workers in a meatpacking industry after the pre-employment medical exam. RESULTS: The results indicate the construction and content validity of the Brazilian Portuguese version for use with a working population and its internal consistency. CONCLUSION: This study resulted in the translation, cultural adaptation, and validation of the Hearing Protection Assessment Questionnaire (HPA), in order to be used to assess the use of individual hearing protection in the occupational field, called Hearing Protection Assessment Questionnaire (HPA).Item Does the age of milk affect its mid-infrared spectrum and predictions(Elsevier Ltd, 2024-05-30) Magro S; Sneddon NW; Costa A; Chiarin E; Penasa M; De Marchi MMilk of dairy species commonly undergo standardized official analyses, these that may require chemical preservation and transportation to a certified laboratory. In this context, storage duration is an important factor that can potential affect both milk chemical analyses and its mid-infrared spectrum. We analysed milk samples at different time points/ages to assess repeatability and reproducibility of mid-infrared predicted traits (e.g., fat and protein). Using spectral data, we also evaluated the ability of spectroscopy coupled with chemometrics to discriminate samples according to their age. Although the main components of milk remained consistently reproducible across age (days), changes in the spectrum due to sample aging and deterioration of the matrix were detectable. Using a discriminant analysis, we achieved a classification accuracy of 77% in validation. Predicting milk age using mid-infrared spectra is feasible, allowing for sample monitoring within circuits where maximum reliability is needed, e.g., bulk or individual milk samples for legal/official use or payment systems.Item Enhancing health outcomes for Māori elders through an intergenerational cultural exchange and physical activity programme: a cross-sectional baseline study(Frontiers Media S.A., 2023-12-12) Oetzel JG; Zhang Y; Nock S; Meha P; Huriwaka H; Vercoe M; Tahu T; Urlich J; Warbrick R; Brown G; Keown S; Rewi P; Erueti B; Warbrick I; Jackson A-M; Perry T; Reddy R; Simpson ML; Cameron MP; Hokowhitu B; Rashedi VBACKGROUND: The study offers baseline data for a strengths-based approach emphasizing intergenerational cultural knowledge exchange and physical activity developed through a partnership with kaumātua (Māori elders) and kaumātua service providers. The study aims to identify the baseline characteristics, along with correlates of five key outcomes. METHODS: The study design is a cross-sectional survey. A total of 75 kaumātua from six providers completed two physical functioning tests and a survey that included dependent variables based in a holistic model of health: health-related quality of life (HRQOL), self-rated health, spirituality, life satisfaction, and loneliness. RESULTS: The findings indicate that there was good reliability and moderate scores on most variables. Specific correlates included the following: (a) HRQOL: emotional support (β = 0.31), and frequent interaction with a co-participant (β = 0.25); (b) self-rated health: frequency of moderate exercise (β = 0.32) and sense of purpose (β = 0.27); (c) spirituality: sense of purpose (β = 0.46), not needing additional help with daily tasks (β = 0.28), and level of confidence with cultural practices (β = 0.20); (d) life satisfaction: sense of purpose (β = 0.57), frequency of interaction with a co-participant (β = -0.30), emotional support (β = 0.25), and quality of relationship with a co-participant (β = 0.16); and (e) lower loneliness: emotional support (β = 0.27), enjoyment interacting with a co-participant (β = 0.25), sense of purpose (β = 0.24), not needing additional help with daily tasks (β = 0.28), and frequency of moderate exercise (β = 0.18). CONCLUSION: This study provides the baseline scores and correlates of important social and health outcomes for the He Huarahi Tautoko (Avenue of Support) programme, a strengths-based approach for enhancing cultural connection and physical activity.Item Predicting replicability—Analysis of survey and prediction market data from large-scale forecasting projects(Public Library of Science (PLoS), 2021-04-14) Gordon M; Viganola D; Dreber A; Johannesson M; Pfeiffer TThe reproducibility of published research has become an important topic in science policy. A number of large-scale replication projects have been conducted to gauge the overall reproducibility in specific academic fields. Here, we present an analysis of data from four studies which sought to forecast the outcomes of replication projects in the social and behavioural sciences, using human experts who participated in prediction markets and answered surveys. Because the number of findings replicated and predicted in each individual study was small, pooling the data offers an opportunity to evaluate hypotheses regarding the performance of prediction markets and surveys at a higher power. In total, peer beliefs were elicited for the replication outcomes of 103 published findings. We find there is information within the scientific community about the replicability of scientific findings, and that both surveys and prediction markets can be used to elicit and aggregate this information. Our results show prediction markets can determine the outcomes of direct replications with 73% accuracy (n = 103). Both the prediction market prices, and the average survey responses are correlated with outcomes (0.581 and 0.564 respectively, both p < .001). We also found a significant relationship between p-values of the original findings and replication outcomes. The dataset is made available through the R package “pooledmaRket” and can be used to further study community beliefs towards replications outcomes as elicited in the surveys and prediction markets.Item Can Psychopathy Be Adaptive at Work? Development and Application of a Work Focused Self- and Other-Report Measure of the Triarchic Psychopathy Model(MDPI (Basel, Switzerland), 2020-06-02) Sutton A; Roche M; Stapleton M; Roemer APsychopathy may have both adaptive and maladaptive effects at work but research into workplace psychopathy is constrained by the lack of short, work-relevant measures that can be used for both self- and other-report. We adapt the Triarchic Psychopathy Measure (TriPM) for this purpose and distinguish the (mal)adaptive effects of psychopathy at work in two time-lagged survey samples. Sample 1 consisted of managers reporting their psychopathic traits and work outcomes (well-being, engagement, burnout and job performance). Sample 2 reported on their managers’ psychopathic traits and leadership styles (servant and abusive supervision) and their own work outcomes. The TriPM (Work) is a reliable, valid, 21-item measure of triarchic psychopathy at work with self- and other-report forms. Using this measure, we demonstrate that the triarchic model’s boldness trait is related to servant leadership and predicts improved well-being and performance while meanness and disinhibition are related to abusive supervision and predict increased burnout.Item First-language raters’ opinions when validating word recordings for a newly developed speech reception threshold test(AOSIS, 2018-03-29) Panday S; Kathard H; Pillay M; Wilson WBackground: The purpose of this study was to consider the value of adding first-language speaker ratings to the process of validating word recordings for use in a new speech reception threshold (SRT) test in audiology. Previous studies had identified 28 word recordings as being suitable for use in a new SRT test. These word recordings had been shown to satisfy the linguistic criteria of familiarity, phonetic dissimilarity and tone, and the psychometric criterion of homogeneity of audibility. Objectives: The aim of the study was to consider the value of adding first-language speakers’ ratings when validating word recordings for a new SRT test. Method: A single observation, cross-sectional design was used to collect and analyse quantitative data in this study. Eleven first-language isiZulu speakers, purposively selected, were asked to rate each of the word recordings for pitch, clarity, naturalness, speech rate and quality on a 5-point Likert scale. The percent agreement and Friedman test were used for analysis. Results: More than 20% of these 11 participants rated the three-word recordings below ‘strongly agree’ in the category of pitch or tone, and one-word recording below ‘strongly agree’ in the categories of pitch or tone, clarity or articulation and naturalness or dialect. Conclusion: The first-language speaker ratings proved to be a valuable addition to the process of selecting word recordings for use in a new SRT test. In particular, these ratings identified potentially problematic word recordings in the new SRT test that had been missed by the previously and more commonly used linguistic and psychometric selection criteria.Item The internal and external consistency of a speech reception threshold test for isiZulu speakers with normal hearing sensitivity(AOSIS, 2018-06-25) Panday S; Kathard H; Pillay M; Wilson WBackground and objectives: This study investigated reliability, particularly the internal and external consistency, of a new isiZulu speech reception threshold (SRT) test. Methods: To examine internal consistency, 21 adult isiZulu speakers with normal hearing sensitivity completed the SRT test using the first and second halves of the SRT wordlist in the same test session. To examine external consistency, a separate 23 adult isiZulu speakers with normal hearing sensitivity completed the SRT test, using the whole word list on two occasions 4 weeks apart. Consistency of SRT test scores in these test conditions was measured using intraclass correlation coefficient analyses (a measure of the consistency or reproducibility of different observations of the same quantity) and Bland and Altman analyses of agreement (a comparison of measurement error with the expected variation amongst subjects). Results: Intraclass correlation coefficient values ranged from 0.69 to 0.79, showing the isiZulu test scores were highly consistent between the test and retest conditions used in this study. Bland and Altman analyses showed that isiZulu speakers with normal hearing sensitivity can be expected to return isiZulu SRT test scores that differ by no more than 7.5 dB HL – 8.7 dB HL between original and repeat assessments. Conclusion: The isiZulu SRT test was reliable, showing high internal and external consistency, when used to assess first-language speakers of isiZulu with normal hearing sensitivity. These findings warrant continued development of the isiZulu SRT test for eventual clinical use. This development should include validating this test on first-language speakers of isiZulu with and without hearing loss.