Multicomponent Metal-Organic Frameworks
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Date
2023-10-26
Open Access Location
Journal Title
Journal ISSN
Volume Title
Publisher
Wiley-VCH GmbH, Weinheim
Rights
(c) 2023 The Author/s
CC BY 4.0
CC BY 4.0
Abstract
Metal-organic frameworks (MOFs) are constructed from metal ions or clusters and organic linkers. Typical MOFs are rather simple, comprising just one type of joint and linker. An additional degree of structural complexity can be introduced by using multiple different components that are assembled into the same framework In the early days of MOF chemistry, conventional wisdom held that attempting to prepare frameworks starting from such a broad set of components would lead to multiple different phases. However, this review highlights how this view was mistaken and frameworks comprising multiple different components can be deliberately designed and synthesized. When coupled to structural order and periodicity, the presence of multiple components leads to exceptional functional properties that can be understood at the atomic level.
Description
Keywords
Complexity, Metal-Organic Frameworks, Multicomponent, Multivariate, Porous Materials
Citation
Lee SJ, Telfer SG. (2023). Multicomponent Metal-Organic Frameworks.. Angew Chem Int Ed Engl. 62. 44. (pp. e202306341-).