Guest size limitation in metal-organic framework crystal-glass composites

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dc.citation.issue13
dc.citation.volume9
dc.contributor.authorAshling CW
dc.contributor.authorMacreadie LK
dc.contributor.authorSouthern TJF
dc.contributor.authorZhang Y
dc.contributor.authorMcHugh LN
dc.contributor.authorEvans RC
dc.contributor.authorKaskel S
dc.contributor.authorTelfer SG
dc.contributor.authorBennett TD
dc.date.accessioned2024-01-11T00:21:31Z
dc.date.accessioned2024-07-25T06:46:17Z
dc.date.available2021-03-01
dc.date.available2024-01-11T00:21:31Z
dc.date.available2024-07-25T06:46:17Z
dc.date.issued2021-03-01
dc.description.abstractMetal-organic framework crystal-glass composites (MOF CGCs) have previously been formed by embedding crystalline MIL-53(Al) within a ZIF-62 glass (agZIF-62) matrix. Here we highlight thermal stability considerations in the formation of MOF CGCs, and subsequently report the synthesis of two novel MOF CGCs, by incorporating MIL-118 and UL-MOF-1 withinagZIF-62. These new materials, alongside the prototypical MOF CGC, formed using MIL-53(Al), were studied using scanning electron microscopy, powder X-ray diffraction, and gas sorption techniques. The gas uptake in composites formed from MIL-118C and UL-MOF-1 is largely dominated by theagZIF-62 matrix, suggesting that to improve the porosity of the MOF CGC, the matrix porosity must be improved, or a percolation threshold must be overcome.
dc.description.confidentialfalse
dc.format.pagination8386-8393
dc.identifier.author-urlhttp://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000637555800019&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=c5bb3b2499afac691c2e3c1a83ef6fef
dc.identifier.citationAshling CW, Macreadie LK, Southern TJF, Zhang Y, McHugh LN, Evans RC, Kaskel S, Telfer SG, Bennett TD. (2021). Guest size limitation in metal-organic framework crystal-glass composites. Journal of Materials Chemistry A. 9. 13. (pp. 8386-8393).
dc.identifier.doi10.1039/d0ta11229a
dc.identifier.eissn2050-7496
dc.identifier.elements-typejournal-article
dc.identifier.issn2050-7488
dc.identifier.urihttps://mro.massey.ac.nz/handle/10179/70837
dc.languageEnglish
dc.publisherRoyal Society of Chemistry
dc.publisher.urihttps://pubs.rsc.org/en/content/articlelanding/2021/TA/D0TA11229A
dc.relation.isPartOfJournal of Materials Chemistry A
dc.rightsCC BY 3.0
dc.rights.urihttps://creativecommons.org/licenses/by/3.0/
dc.titleGuest size limitation in metal-organic framework crystal-glass composites
dc.typeJournal article
pubs.elements-id444401
pubs.organisational-groupOther
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