Breaking paracyclophane: the unexpected formation of non-symmetric disubstituted nitro [2.2] metaparacyclophanes
dc.citation.volume | 17 | |
dc.contributor.author | Patel S | |
dc.contributor.author | Dais TN | |
dc.contributor.author | Plieger PG | |
dc.contributor.author | Rowlands GJ | |
dc.coverage.spatial | Germany | |
dc.date.accessioned | 2023-12-15T01:13:57Z | |
dc.date.accessioned | 2024-07-25T06:36:42Z | |
dc.date.available | 2021-06-29 | |
dc.date.available | 2023-12-15T01:13:57Z | |
dc.date.available | 2024-07-25T06:36:42Z | |
dc.date.issued | 2021 | |
dc.description.abstract | Substituted [2.2]metaparacyclophanes are amongst the least studied of the simple cyclophanes. This is undoubtedly the result of the lengthy syntheses of these compounds. We report the simple synthesis of a rare example of a non-symmetric [2.2]metaparacyclophane. Treatment of [2.2]paracyclophane under standard nitration conditions gives a mixture of 4-nitro[2.2] paracyclophane, 4-hydroxy-5-nitro [2.2] metaparacyclophane and a cyclohexadienone cyclophane. | |
dc.format.pagination | 1518-1526 | |
dc.identifier.author-url | https://www.ncbi.nlm.nih.gov/pubmed/34285723 | |
dc.identifier.citation | Patel S, Dais TN, Plieger PG, Rowlands GJ. (2021). Breaking paracyclophane: the unexpected formation of non-symmetric disubstituted nitro[2.2]metaparacyclophanes.. Beilstein J Org Chem. 17. (pp. 1518-1526). | |
dc.identifier.doi | 10.3762/bjoc.17.109 | |
dc.identifier.eissn | 1860-5397 | |
dc.identifier.elements-type | journal-article | |
dc.identifier.issn | 1860-5397 | |
dc.identifier.uri | https://mro.massey.ac.nz/handle/10179/70534 | |
dc.language | eng | |
dc.publisher | Beilstein-Institut | |
dc.relation.isPartOf | Beilstein J Org Chem | |
dc.rights | (c) The author/s | en |
dc.rights.license | CC BY 4.0 | en |
dc.rights.uri | https://creativecommons.org/licenses/by/4.0/ | en |
dc.subject | cyclophane | |
dc.subject | metaparacyclophane | |
dc.subject | nitration | |
dc.subject | paracyclophane | |
dc.subject | rearrangement | |
dc.title | Breaking paracyclophane: the unexpected formation of non-symmetric disubstituted nitro [2.2] metaparacyclophanes | |
dc.type | Journal article | |
pubs.elements-id | 447508 | |
pubs.organisational-group | Other |