NMR studies of internal rotation : a thesis presented in partial fulfilment of the requirements for the degree of Doctor of Philosophy in Chemistry at Massey University

Simple item page
dc.contributor.authorFurness, Alan Robert
dc.date.accessioned2012-09-10T02:15:05Z
dc.date.available2012-09-10T02:15:05Z
dc.date.issued1975
dc.description.abstractDensity matrix theory has been used to develop a computer program for the solution of a four-nuclear spin system. A description of the theory used to develop this program is given in Chapter Three. This theory has been used to study a range of p-substituted nitrosobenzenes. The activation parameters have been determined and for N,N-dimethyl-p-nitrosoaniline, a comparison has been made with previous studies which have used more approximate methods. The solvent dependency of the barrier to rotation has been investigated in the N,N-dialkyl-p-nitrosoanilines and no significant solvent dependence found. In the early stages of this thesis, attempts were made to find a tetrahedral cobalt (II) complex involving ligand exchange, but no such complex suitable for a detailed NMR investigation was found. The investigation, though unsuccessful, has been briefly reported. These findings may aid further work in this area.en
dc.identifier.urihttp://hdl.handle.net/10179/3804
dc.language.isoenen
dc.publisherMassey Universityen_US
dc.rightsThe Authoren_US
dc.subjectNuclear magnetic resonance (NMR)en
dc.subjectNuclear spin systemen
dc.subjectNitrosobenzeneen
dc.subjectDensity matrixen
dc.titleNMR studies of internal rotation : a thesis presented in partial fulfilment of the requirements for the degree of Doctor of Philosophy in Chemistry at Massey Universityen
dc.typeThesisen
massey.contributor.authorFurness, Alan Roberten
thesis.degree.disciplineChemistryen
thesis.degree.grantorMassey Universityen
thesis.degree.levelDoctoralen
thesis.degree.nameDoctor of Philosophy (Ph.D.)en
Files
Original bundle
Now showing 1 - 2 of 2
Thumbnail Image
Name:
02_whole.pdf
Size:
8.6 MB
Format:
Adobe Portable Document Format
Description:
Download
Thumbnail Image
Name:
01_front.pdf
Size:
2.18 MB
Format:
Adobe Portable Document Format
Description:
Download
License bundle
Now showing 1 - 1 of 1
Thumbnail Image
Name:
license.txt
Size:
804 B
Format:
Item-specific license agreed upon to submission
Description:
Download
Collections
Theses and Dissertations