Journal Articles

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Subject: search.filters.subject.0912 Materials Engineering

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Now showing 1 - 5 of 5
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    Formulation and characterization of polyester-lignite composite coated slow-release fertilizers
    (Springer Nature Switzerland AG, 26/09/2022) Gunaratnam A; Bishop P; Jeyakumar P; Grafton M; Davies CE; McCurdy M
    Two polyester-lignite composite coated urea slow-release fertilizers (SRFs; Poly3 and Poly5) were developed and their physicochemical properties were studied. Both these SRFs significantly (p < 0.05) extended the urea release compared to uncoated urea; Poly3 and Poly5 by 117 and 172 h, respectively. The urea release characteristics of Poly5 were further enhanced by linseed oil application (Poly5-linseed). The SEM images demonstrated the coatings were in contact with the urea and encase urea particles completely with the average coating thickness of 167.2 ± 15 µm. The new interactions between polyester and lignite in the composite coating were confirmed by the FTIR analysis. Polyester-calcium carbonate (Polyester-CaCO3) coated SRFs (Calc3 and Calc5) were developed using CaCO3 as a filler in place of lignite and the urea dissolution rate was compared with Poly3 and Poly5. The urea release times for the polyester-CaCO3 formulations, 48 and 72 h, were significantly (P < 0.05) lower than the polyester-lignite formulation, showing that lignite imparted greater control over release time than CaCO3. Findings from this work showed that polyester-lignite composites can be used as a coating material for SRFs.
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    The effects of dispersion on time-of-flight acoustic velocity measurements in a wooden rod
    (Elsevier BV, 2023-03) Bakar AHA; Legg M; Konings D; Alam F
    The stiffness of wood can be estimated from the acoustic velocity in the longitudinal direction. Studies have reported that stiffness measurements obtained using time-of-flight acoustic velocity measurements are overestimated compared to those obtained using the acoustic resonance and bending test methods. More research is needed to understand what is causing this phenomenon. In this work, amplitude threshold time-of-flight, resonance, and guided wave measurements are performed on wooden and aluminium rods. Using guided wave theory, it is shown through simulations and experimental results that dispersion causes an overestimation of time-of-flight measurements. This overestimation was able to be mitigated using dispersion compensation. However, other guided wave techniques could potentially be used to obtain improved measurements.
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    Edible films from essential-oil-loaded nanoemulsions: Physicochemical characterization and antimicrobial properties
    (1/05/2015) Acevedo-Fani A; Salvia-Trujillo L; Rojas-Graü MA; Martín-Belloso O
    Edible films including active ingredients can be used as an alternative to preserve food products. Essential oils (EOs) exhibit antimicrobial activity against pathogenic microorganisms but their low water solubility limits the application in foods. To improve water dispersion and protect EOs from degradation, nano-sized emulsions emerge as a viable alternative. Nanoemulsions containing EOs and polysaccharides could be used to form edible films with functional properties. This study was focused on the evaluation of physical, mechanical and antimicrobial properties of alginate-based edible films formed from nanoemulsions of EOs. Nanoemulsions containing thyme (TH-EO), lemongrass (LG-EO) or sage (SG-EO) oil as dispersed phase and sodium alginate solution as continuous phase were prepared. The average droplet size of nanoemulsions was reduced after the microfluidization treatment exhibiting multimodal size distributions. The ζ-potentials of nanoemulsions were between-41mV and-70mV depending on the type of EO used. The lowest whiteness index was found in SG-EO nanoemulsions, whereas those containing TH-EO showed the highest value. Films formed from SG-EO nanoemulsions exhibited higher transparency, water vapor resistance and flexibility than films formed from TH-EO or LG-EO. Edible films containing TH-EO were those with the strongest antimicrobial effect against inoculated Escherichia coli, achieving up to 4.71Log reductions after 12h. Results obtained in the present work evidence the suitability of using nanoemulsions with active ingredients for the formation of edible films, with different physical and functional properties.
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    All-Dielectric Transreflective Angle-Insensitive Near-Infrared (NIR) Filter
    (MDPI (Basel, Switzerland), 2022-08) Shaukat A; Umer R; Noble F; Arif K
    This paper presents an all-dielectric, cascaded, multilayered, thin-film filter, allowing near-infrared filtration for spectral imaging applications. The proposed design is comprised of only eight layers of amorphous silicon (A-Si) and silicon nitride (Si₃N₄), successively deposited on a glass substrate. The finite difference time domain (FDTD) simulation results demonstrate a distinct peak in the near-infrared (NIR) region with transmission efficiency up to 70% and a full-width-at-half-maximum (FWHM) of 77 nm. The theoretical results are angle-insensitive up to 60⁰ and show polarization insensitivity in the transverse magnetic (TM) and transverse electric (TE) modes. The theoretical response, obtained with the help of spectroscopic ellipsometry (SE), is in good agreement with the experimental result. Likewise, the experimental results for polarization insensitivity and angle invariance of the thin films are in unison with the theoretical results, having an angle invariance up to 50⁰.
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    Acoustic Multi-Detection of Gliadin Using QCM Crystals Patterned with Controlled Sectors of TEM Grid and Annealed Nanoislands on Gold Electrode
    (MDPI (Basel, Switzerland), 20/04/2020) Casari Bariani G; Zhou L; Poggesi S; Mittapalli R; Manzano M; Ionescu RE
    Celiac diseases are a group of gluten ingestion-correlated pathologies that are widespread and, in some cases, very dangerous for human health. The only effective treatment is the elimination of gluten from the diet throughout life. Nowadays, the food industries are very interested in cheap, easy-to-handle methods for detecting gluten in food, in order to provide their consumers with safe and high-quality food. Here, for the first time, the manufacture of controlled micropatterns of annealed gold nanoislands (AuNIs) on a single QCM crystal (QCM-color) and their biofunctionalization for the specific detection of traces of gliadin is reported. In addition, the modified quartz crystal with a TEM grid and 30 nm Au (Q-TEM grid crystal) is proposed as an acoustic sensitive biosensing platform for the rapid screening of the gliadin content in real food products.